Topological studies of three related metal-organic frameworks of Gd III and 5-nitroisophthalate

Simple item page
dc.contributor.authorDavies, Kate
dc.contributor.authorBourne, Susan A
dc.contributor.authorÖhrström, Lars
dc.contributor.authorOliver, Clive L
dc.date.accessioned2021-10-08T11:06:56Z
dc.date.available2021-10-08T11:06:56Z
dc.date.issued2012
dc.description.abstractThe reaction of 5-nitroisophthalic acid (H(2)NIA) with Gd(NO(3))(3)·6H(2)O in DMF afforded three new metal-organic frameworks: [Gd(NIA)(1.5)(DMF)(2)]·DMF (I), [Gd(2)(NIA)(3)(DMF)(4)]·xH(2)O (II) and [Gd(4)(NIA)(6)(DMF)(5.5)(H(2)O)(3)]·4DMF·H(2)O (III). These compounds can be prepared through a variety of methods. Compounds (I) and (II) are more reproducibly formed than compound (III). Network analysis revealed (I) to have a (4(12).6(3))-pcu topology, while (II) displays a (4(2).8(4))(4(2).8(4))-pts topology. Compound (III) was found to present the uncommon 4,5,6T11 topological net, which combines aspects of both the pcu and pts topologies. The short symbol of this net is (4(4).6(2))(4(6).6(4))(2)(4(8).6(6).8).
dc.identifier.apacitationDavies, K., Bourne, S. A., , & Oliver, C. L. (2012). Topological studies of three related metal-organic frameworks of Gd III and 5-nitroisophthalate. <i>Acta Crystallographica. Section B - Structural Science</i>, 68(5), 528 - 535. http://hdl.handle.net/11427/35122en_ZA
dc.identifier.chicagocitationDavies, Kate, Susan A Bourne, , and Clive L Oliver "Topological studies of three related metal-organic frameworks of Gd III and 5-nitroisophthalate." <i>Acta Crystallographica. Section B - Structural Science</i> 68, 5. (2012): 528 - 535. http://hdl.handle.net/11427/35122en_ZA
dc.identifier.citationDavies, K., Bourne, S.A., & Oliver, C.L. 2012. Topological studies of three related metal-organic frameworks of Gd III and 5-nitroisophthalate. <i>Acta Crystallographica. Section B - Structural Science.</i> 68(5):528 - 535. http://hdl.handle.net/11427/35122en_ZA
dc.identifier.issn0108-7681
dc.identifier.issn1600-5740
dc.identifier.ris TY - Journal Article AU - Davies, Kate AU - Bourne, Susan A AU - Öhrström, Lars AU - Oliver, Clive L AB - The reaction of 5-nitroisophthalic acid (H(2)NIA) with Gd(NO(3))(3)·6H(2)O in DMF afforded three new metal-organic frameworks: [Gd(NIA)(1.5)(DMF)(2)]·DMF (I), [Gd(2)(NIA)(3)(DMF)(4)]·xH(2)O (II) and [Gd(4)(NIA)(6)(DMF)(5.5)(H(2)O)(3)]·4DMF·H(2)O (III). These compounds can be prepared through a variety of methods. Compounds (I) and (II) are more reproducibly formed than compound (III). Network analysis revealed (I) to have a (4(12).6(3))-pcu topology, while (II) displays a (4(2).8(4))(4(2).8(4))-pts topology. Compound (III) was found to present the uncommon 4,5,6T11 topological net, which combines aspects of both the pcu and pts topologies. The short symbol of this net is (4(4).6(2))(4(6).6(4))(2)(4(8).6(6).8). DA - 2012 DB - OpenUCT DP - University of Cape Town IS - 5 J1 - Acta Crystallographica. Section B - Structural Science LK - https://open.uct.ac.za PY - 2012 SM - 0108-7681 SM - 1600-5740 T1 - Topological studies of three related metal-organic frameworks of Gd III and 5-nitroisophthalate TI - Topological studies of three related metal-organic frameworks of Gd III and 5-nitroisophthalate UR - http://hdl.handle.net/11427/35122 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/35122
dc.identifier.vancouvercitationDavies K, Bourne SA, , Oliver CL. Topological studies of three related metal-organic frameworks of Gd III and 5-nitroisophthalate. Acta Crystallographica. Section B - Structural Science. 2012;68(5):528 - 535. http://hdl.handle.net/11427/35122.en_ZA
dc.language.isoeng
dc.publisher.departmentDepartment of Chemistry
dc.publisher.facultyFaculty of Science
dc.sourceActa Crystallographica. Section B - Structural Science
dc.source.journalissue5
dc.source.journalvolume68
dc.source.pagination528 - 535
dc.source.urihttps://dx.doi.org/10.1107/S0108768112032053
dc.subject.othercoordination polymers
dc.subject.othercrystal-structures
dc.subject.otherreticular chemistry
dc.subject.othernet
dc.subject.othertopology
dc.subject.otherdesign
dc.subject.otherluminescence
dc.subject.othercomplexes
dc.subject.otherligands
dc.subject.othersites
dc.subject.otherphotoluminescence
dc.titleTopological studies of three related metal-organic frameworks of Gd III and 5-nitroisophthalate
dc.typeJournal Article
uct.type.publicationResearch
uct.type.resourceJournal Article
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
DaviesKate_Topological_stu_2012.pdf
Size:
1.94 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Journal Articles